The latest challengers for Marvel vs. Capcom 3: Fate of Two Worlds? Spider-Man and Wesker from Resident Evil. This is certainly not the first appearance for Spider-Man in a MvC title. It is, however, for Wesker.
These are the latest characters in the span of the past two weeks. Earlier, Marvel's X-23 and Capcom's Tron Bonne were added to the roster.
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Marvel vs. Capcom 3: Fate of Two Worlds will be out next spring on the PlayStation 3 and Xbox 360.
Character Reveal: Spider-Man and Wesker [Gamespot]